Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters.

نویسندگان

  • Caleb D Martin
  • Cory M Weinstein
  • Curtis E Moore
  • Arnold L Rheingold
  • Guy Bertrand
چکیده

The reaction of cyclic di(amido)- and (alkyl)(amino)-carbenes with white phosphorus in benzene afford P8 clusters supported by four carbenes, or a novel type of carbene-P4 adduct.

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عنوان ژورنال:
  • Chemical communications

دوره 49 40  شماره 

صفحات  -

تاریخ انتشار 2013